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The Resource Organometallic chemistry, Volume 38, edited by Ian J.S. Fairlamb & Jason M. Lynam

Organometallic chemistry, Volume 38, edited by Ian J.S. Fairlamb & Jason M. Lynam

Contributor
Summary
A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge Muller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields
Language
eng
Work
Publication
Extent
1 online resource
Contents
  • Preface; Organometallic Aspects of C-H Activation / Functionalisation; New Developments in the Biomedical Chemistry of Transition Metal Complexes; From Small Molecules to Nanotheranostics Design; TBC; Group 1; Organo-transition Metal Cluster Complexes; The Application of NACNAC Complexes; Synthesis and Application of Novel Primary Phosphine Ligands: Part 2
Isbn
9781849734868
Instance
Label
Organometallic chemistry, Volume 38
Title
Organometallic chemistry
Title number
Volume 38
Statement of responsibility
edited by Ian J.S. Fairlamb & Jason M. Lynam
Contributor
Subject
Genre
Language
eng
Summary
A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge Muller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields
Member of
Cataloging source
UKRSC
Dewey number
547.05
Index
no index present
LC call number
QD410
LC item number
.O74 v.38
Literary form
non fiction
Nature of contents
dictionaries
http://library.link/vocab/relatedWorkOrContributorName
  • Fairlamb, Ian J. S
  • Lynam, Jason M
Series statement
Specialist Periodical Reports
http://library.link/vocab/subjectName
  • Organometallic chemistry
  • SCIENCE
  • Organometallic chemistry
Label
Organometallic chemistry, Volume 38, edited by Ian J.S. Fairlamb & Jason M. Lynam
Instantiates
Publication
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Preface; Organometallic Aspects of C-H Activation / Functionalisation; New Developments in the Biomedical Chemistry of Transition Metal Complexes; From Small Molecules to Nanotheranostics Design; TBC; Group 1; Organo-transition Metal Cluster Complexes; The Application of NACNAC Complexes; Synthesis and Application of Novel Primary Phosphine Ligands: Part 2
Control code
819343534
Dimensions
unknown
Extent
1 online resource
Form of item
online
Isbn
9781849734868
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
http://library.link/vocab/ext/overdrive/overdriveId
t3663
Specific material designation
remote
System control number
(OCoLC)819343534
Label
Organometallic chemistry, Volume 38, edited by Ian J.S. Fairlamb & Jason M. Lynam
Publication
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Preface; Organometallic Aspects of C-H Activation / Functionalisation; New Developments in the Biomedical Chemistry of Transition Metal Complexes; From Small Molecules to Nanotheranostics Design; TBC; Group 1; Organo-transition Metal Cluster Complexes; The Application of NACNAC Complexes; Synthesis and Application of Novel Primary Phosphine Ligands: Part 2
Control code
819343534
Dimensions
unknown
Extent
1 online resource
Form of item
online
Isbn
9781849734868
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
http://library.link/vocab/ext/overdrive/overdriveId
t3663
Specific material designation
remote
System control number
(OCoLC)819343534

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